Researchers from Johns Hopkins College, the East China College of Science and Expertise, Stony Brook College, the Brookhaven Nationwide Laboratory, Soochow College, the École Polytechnique Fédérale de Lausanne (EPFL), and Lawrence Berkeley Nationwide Laboratory have give you a course of and the mandatory supplies that, they are saying, might assist hold Moore’s Regulation on observe by making it potential to proceed shrinking semiconductor characteristic sizes — utilizing a lithographic course of “past excessive ultraviolet radiation.”
“Firms have their roadmaps of the place they need to be in 10 to twenty years and past,” explains co-corresponding creator Michael Tsapatsis, professor of chemical and biomolecular engineering at Johns Hopkins College, by means of background to the crew’s work. “One hurdle has been discovering a course of for making smaller options in a manufacturing line the place you irradiate supplies rapidly and with absolute precision to make the method economical.”
Researchers are hoping {that a} new method to coat a silicon wafer in a B-EUV-compatible resist will hold Moore’s Regulation alive. (📷: Miao et al.)
The march of know-how has seen, traditionally, the variety of transistors on a modern semiconductor chip development in direction of a doubling roughly each two years — an statement by Intel co-founder Gordon Moore, which has turn into a must-hit goal for the business. To realize that with out ballooning processors to the dimensions of soccer pitches, the transistors and different parts should get smaller — however right now, on the planet of single-digit nanometer characteristic sizes, that is an actual problem.
As a way to create chips with ultra-small characteristic sizes, the lithographic course of has by necessity taken a flip for the energetic: modern chips are right now constructed utilizing excessive ultraviolet (EUV) lithography — however even that has its limits, which is the place crew’s work comes into play: past excessive ultraviolet lithography (B-EUV).
There are two key components to the lithographic course of. The primary is the laser, and the second is the resist — a cloth that reacts with the laser radiation to etch patterns into the silicon. Conventional resists do not work effectively with high-energy B-EUV laser sources — however resists created from imidazole-based metal-organic supplies do. The crew’s key contribution: a method to coat the silicon wafer with this new imidazole-based resist, dubbed chemical liquid deposition (CLD), and a path to straightforward experimentation to find different supplies that might work for B-EUV semiconductor manufacturing.
The strategy has been confirmed in a lab, however not but at a business scale. (📷: Xinpei Zhou/Johns Hopkins College)
“By enjoying with the 2 parts (metallic and imidazole), you’ll be able to change the effectivity of absorbing the sunshine and the chemistry of the next reactions. And that opens us as much as creating new metal-organic pairings,” Tsapatsis explains. “The thrilling factor is there are no less than 10 totally different metals that can be utilized for this chemistry, and tons of of organics. As a result of totally different wavelengths have totally different interactions with totally different parts, a metallic that could be a loser in a single wavelength generally is a winner with the opposite. Zinc isn’t superb for excessive ultraviolet radiation, but it surely’s the most effective for the B-EUV.”
The crew’s work has been printed below closed-access phrases within the journal Nature Chemical Engineering.

